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Page Title: TYPES OF HAZARDOUS MATERIALS
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HAZARDOUS  MATERIAL  STORAGE
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Aviation Storekeeper 1 & C - Aviation theories and other practices
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Compressed  Gases

with  the  controllers  located  outside  the  compartment. Flammable  items  requiring  stowage  in  the  flammable liquids  storeroom  are  assigned  Hazard  Characteristic Codes   (HCCs)   or   special   material   content   codes (SMCCs) in the HMIS as follows Liquids: Codes F, J1, G, P (when applicable to wood alcohol) Pastes,  greases,  and  other  semisolids:  Code  G Solids: Code J2 ACID  LOCKER An acid locker is a leak-proof lead-linedbox, chest, or  locker  especially  designed  for  stowing  bottles  or carboys of acid. A label bearing the inscription ACID BOTTLE  STOWAGE  in  3/8-inch  letters  must  be securely attached to the lid of each acid locker. Acid lockers for flammable acids are kept in the flammable liquids  storeroom.  However,  acid  lockers  that  contain only medical acids may be kept in a medical storeroom under   the   custody   of   the   medical   department representative. Items that must be kept in the acid locker  are  assigned  Special  Material  Content  Code (SMCC) “C” in the HMIS. Nitric acid, which is coded Cl, must be kept in the acid locker. ALCOHOL   LOCKER An  alcohol  locker  is  a  chest  or  locker  used  for security  stowage  of  grain  alcohols  that  are  highly susceptible  to  pilferage  (that  is,  ethanol  or  ethyl alcohol).  Alcohol  lockers  are  located  in  the  flammable liquids  storeroom.  However,  lockers  that  contain  only medicinal  alcohol  (100  proof  or  less)  maybe  located  in any  secure  space  designated  by  the  commanding officer, as described in chapter 1, paragraph 1118-4c of NAVSUP  P485. TYPES OF HAZARDOUS MATERIALS Some materials have inherent properties that make them hazardous to personnel, to the ship, or to both. These materials can be stowed safely when the proper care and precautions are taken. Acid Stow  liquid  inorganic  acids,  such  as  hydrochloric, sulfuric, nitric, an phosphoric, bottled in glass or plastic in such a manner that they are cushioned against shock. They should be kept in their original shipping carton inside  suitable  acid-resistant  lockers,  cabinets,  or chests,  located  in  storerooms  below  the  full-load waterline. Except where stowed in chests or lockers, the lower part  of  the  bulkhead  where  acids  are  stowed  must  be covered  with  a  watertight  rubber  lining.  A  label inscribed   ACID   BOTTLE   STOWAGE   in   3/8-inch letters must be attached securely to the outside of the storeroom  door.  Acids  should  be  stowed  separately from  oxidizing  or  flammable  materials.  Corrosive acids (or vapors) must not be allowed to come in contact with the skin ore yes. Storeroom custodians who stow or issue these acids should wear rubber gloves, rubber aprons, and goggles to protect themselves and their clothing from acid burns. Alkalies Alkaline  materials  are  also  classified  as  corrosives, but  have  different  chemical  properties  from  acids. Alkalies, such as lithium hydroxide, sodium hydroxide, lye,  phosphates,  laundry  products,  and  oven  cleaners must  be  stowed  in  designated  lockers,  cabinets,  or chests,  separated  from  acids,  oxidizers,  and  other incompatible materials. Ensure the stowage area is dry. Alcohol Since most commonly used alcohols have a flash point below 100°F, all alcohol will be stowed in the flammable liquids storeroom. Not all alcohol is readily identifiable by name. For  example,  many  lacquer thinners  have  methanol  (wood  alcohol),  which  is extremely  poisonous,  as  the  principal  ingredient.  The HMIS identifies these items by name and NSN. As stated  before,  grain  alcohol  (ethanol  or  ethyl  alcohol) must be stowed in an alcohol locker. Oxidizing Material Many  shipboard  fires  with  resultant  fatalities  have been attributed to improper stowage or handling of oxidizing  materials,  particularly  calcium  hypochlorite. Oxidizing materials listed in the HMIS are identified by HCC “D” SMCC “J.” Nitric acid, a strong oxidizer, must be stowed in the acid locker. Oxygen, gas, and calcium hypochlorite must be stowed according to the following paragraphs on calcium hypochlorite and compressed gases.  All  other  oxidizers  are  stowed  in  a  dry compartment, away from combustible materials. 2-15

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