Some materials readily give up their electrons and others readily accept electrons. For example, when two dissimilar metals like copper and zinc are joined together, a transfer of electrons can take place. Electrons will leave the copper atoms and enter the zinc atoms. The zinc gets a surplus of electrons and becomes negatively charged. The copper loses electrons and takes on a positive charge. This creates a voltage potential across the junction of the two metals. The heat energy of normal room temperature is enough to make them release and gain electrons, causing a measurable voltage potential. As more heat energy is applied to the junction, more electrons are released, and the voltage potential becomes greater, as shown in Figure 15. When heat is removed and the junction cools, the charges will dissipate and the voltage potential will decrease. This process is called thermoelectricity. A device like this is generally referred to as a "thermocouple."

The thermoelectric voltage in a thermocouple is dependent upon the heat energy applied to the junction of the two dissimilar metals. Thermocouples are widely used to measure temperature and as heat-sensing devices in automatic temperature controlled equipment.

Figure 15 Heat Energy Causes Copper to Give up Electrons to Zinc

Thermocouple power capacities are very small compared to some other sources, but are somewhat greater than those of crystals.

Generally speaking, a thermocouple can be subjected to higher temperatures than ordinary mercury or alcohol thermometers.