The size and mass of atoms are so small that the use of normal measuring units, while possible, is often inconvenient. Units of measure have been defined for mass and energy on the atomic scale to make measurements more convenient to express. The unit of measure for mass is the atomic mass unit (amu). One atomic mass unit is equal to 1.66 x 10^-24 grams. The reason for this particular value for the atomic mass unit will be discussed in a later chapter. Note from Table 1 that the mass of a neutron and a proton are both about 1 amu. The unit for energy is the electron volt (eV). The electron volt is the amount of energy acquired by a single electron when it falls through a potential difference of one volt. One electron volt is equivalent to 1.602 x 10^-19 joules or 1.18 x 10^-19 foot-pounds.

Nuclides

The total number of protons in the nucleus of an atom is called the atomic number of the atom and is given the symbol Z. The number of electrons in an electrically-neutral atom is the same as the number of protons in the nucleus. The number of neutrons in a nucleus is known as the neutron number and is given the symbol N. The mass number of the nucleus is the total number of nucleons, that is, protons and neutrons in the nucleus. The mass number is given the symbol A and can be found by the equation Z + N = A.

Each of the chemical elements has a unique atomic number because the atoms of different elements contain a different number of protons. The atomic number of an atom identifies the particular element.

Each type of atom that contains a unique combination of protons and neutrons is called a nuclide. Not all combinations of numbers of protons and neutrons are possible, but about 2500 specific nuclides with unique combinations of neutrons and protons have been identified. Each nuclide is denoted by the chemical symbol of the element with the atomic number written as a subscript and the mass number written as a superscript, as shown in Figure 2. Because each element has a unique name, chemical symbol, and atomic number, only one of the three is necessary to identify the element. For this reason nuclides can also be identified by either the chemical name or the chemical symbol followed by the mass number (for example, U-235 or uranium-235).

Figure 2 Nomenclature for Identifying Nuclides

Another common format is to use the abbreviation of the chemical element with the mass number superscripted (for example, 235U). In this handbook the format used in the text will usually be the element's name followed by the mass number. In equations and tables, the format in Figure 2 will usually be used.

Example:

State the name of the element and the number of protons, electrons, and neutrons in the nuclides listed below.

Solution:

The name of the element can be found from the Periodic Table (refer to Chemistry Fundamentals Handbook) or the Chart of the Nuclides (to be discussed later). The number of protons and electrons are equal to Z. The number of neutrons is equal to Z-A.